On the same £65,000 gross, a worker takes home roughly $11,742 more per year in Mexico than in United Kingdom. That gap reflects the tax structure alone — before rent, healthcare, or savings behaviour come into play.
Housing is the first multiplier. Mexico has low rent pressure, while United Kingdom has high rent pressure. That keeps Mexico's nominal advantage closer to a real-world advantage.
Healthcare and pensions go in the opposite direction. Mexico runs a mixed healthcare model — IMSS and ISSSTE for employees; private clinics widely used. United Kingdom uses a universal model — NHS provides universal care funded from general taxation, with private top-ups. The country with lower take-home often shifts costs that the other country leaves to your private budget.
Net-of-everything, a relocation decision should weigh basic public welfare in Mexico against strong public welfare in United Kingdom, plus differences in pension capture, social safety nets, and city-level cost of living.