On the same 65 000 € gross, a worker takes home roughly 1.819 € more per year in Germany than in Belgium. That gap reflects the tax structure alone — before rent, healthcare, or savings behaviour come into play.
Housing is the first multiplier. Belgium has moderate rent pressure, while Germany has moderate rent pressure. The two markets behave similarly, so most of the gross-to-net advantage flows straight into disposable income.
Healthcare and pensions go in the opposite direction. Belgium runs a universal healthcare model — Mutuelle/ziekenfonds covers most costs after a small co-pay. Germany uses a public model — Statutory health insurance (~14.6% split with employer) gives full coverage. The country with lower take-home often shifts costs that the other country leaves to your private budget.
Net-of-everything, a relocation decision should weigh comprehensive welfare state in Belgium against comprehensive welfare state in Germany, plus differences in pension capture, social safety nets, and city-level cost of living.